Environmental effect on the laser-excited fluorescence spectra of Methylene Blue and Methylene Green dyes

被引:28
作者
Jayaraj, SE
Umadevi, M
Ramakrishnan, V [1 ]
机构
[1] American Coll, Dept Phys, Madurai 625002, Tamil Nadu, India
[2] Madurai Kamaraj Univ, Laser Lab, Dept Microprocessor & Comp, Sch Phys, Madurai 625021, Tamil Nadu, India
关键词
cmc value; fluorescence; polarisation anisotropy; surfactant;
D O I
10.1023/A:1011837930422
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A laser-induced fluorescence investigation of the phenothiazine dyes Methylene Blue (MB) and Methylene Green (MG(+)) is reported. To study the effect of environment, fluorescence spectra of these molecules in a variety of solvents with different polarity and various concentrations of an anionic surfactant were measured. The polarization and anisotropy analysis showed that there is no abrupt behavior except at the surfactant concentrations corresponding to the critical micellar concentration.
引用
收藏
页码:203 / 206
页数:4
相关论文
共 8 条
[1]   Effects of carbohydrates on the solution properties of surfactants and dye-micelle complexation [J].
Acharya, KR ;
Bhattacharyya, SC ;
Moulik, SP .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1999, 122 (01) :47-52
[2]  
LOEFROTH JE, 1982, J PHYS CHEM-US, V86, P1636
[3]   EFFECT OF SODIUM DODECYL-SULFATE ON THE ORIENTATIONAL BEHAVIOR OF A HYDROPHOBIC PROBE IN A C-18-MONOLAYER BONDED TO SILICA [J].
MONTGOMERY, ME ;
WIRTH, MJ .
ANALYTICAL CHEMISTRY, 1992, 64 (21) :2566-2569
[4]   SEARCH FOR A REALISTIC VIEW OF HYDROPHOBIC EFFECTS [J].
MULLER, N .
ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (01) :23-28
[5]   Solvation dynamics of coumarin 480 in micelles [J].
Sarkar, N ;
Datta, A ;
Das, S ;
Bhattacharyya, K .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (38) :15483-15486
[6]   SERS STUDIES ON 1-4 DIHYDROXYANTHRAQUINONE AT AG ELECTRODE [J].
SRIKANTH, VG ;
JAYARAJ, SE ;
RAMAKRISHNAN, V .
PRAMANA-JOURNAL OF PHYSICS, 1993, 41 (05) :467-472
[7]  
*WB SAUND CO, 1938, PATH TECHN, P171
[8]   MICELLES - PHYSICAL-CHEMISTRY OF SURFACTANT ASSOCIATION [J].
WENNERSTROM, H ;
LINDMAN, B .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1979, 52 (01) :1-86