NMR:: A powerful tool in the characterization of coal tar pitch

被引:114
作者
Díaz, C [1 ]
Blanco, CG [1 ]
机构
[1] CSIC, Inst Nacl Carbon, INCAR, E-33080 Oviedo, Spain
关键词
D O I
10.1021/ef020114r
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 [动力工程及工程热物理]; 0820 [石油与天然气工程];
摘要
The application of NMR to coal tar pitch (CTP) characterization provides valuable information about its structure. The DEPT sequence is revealed as a useful tool to identify the different carbon types of CTP components in C-13 NMR spectra. Consequently, chemical shift classifications can be established in an easy and accurate way for C-13 NMR spectra. The resulting spectral regions can be integrated and, hence, the CTP structure characterized. H-1 and C-13 NMR experiments are carried out and integration data calculated. From them, some relationships are defined and significant information about both the external and internal framework of CTP aromatic structures is obtained.
引用
收藏
页码:907 / 913
页数:7
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