Spatial correlations in polycarbonates:: Neutron scattering and simulation

被引：66

作者：

Eilhard, J

Zirkel, A

Tschöp, W

Hahn, O

Kremer, K

Schärpf, O

Richter, D

Buchenau, U

机构：

[1] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany

[2] Max Planck Inst Polymer Res, D-55021 Mainz, Germany

[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 110卷 / 03期

关键词：

D O I：

10.1063/1.477889

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present the results of a combined experimental (neutron scattering) and theoretical (computer simulation) effort to investigate structural properties of polycarbonate melts and glasses in the wave vector regime of Q less than or equal to 2.2 Angstrom(-1). The experimental part consists of advanced spin polarized scattering experiments, allowing us to extract the coherent scattering for protonated and deuterated samples. The simulations employ recently developed novel mapping procedures, which allow us to efficiently equilibrate complex polymer melts, thereby reproducing the experiment in much closer detail than earlier attempts. (C) 1999 American Institute of Physics. [S0021-9606(99)50603-X].

引用

页码：1819 / 1830

页数：12

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