Optically active β-ketoiminato cationic cobalt(III) complexes:: Efficient catalysts for enantioselective carbonyl-ene reaction of glyoxal derivatives

被引：60

作者：

Kezuka, S ^{[1
]}

Ikeno, T ^{[1
]}

Yamada, T ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol015980m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHCIS] Optically active beta -ketoiminato cationic cobalt(lll) complexes were synthesized as effective Lewis acid catalysts for the enantioselective carbonylene reaction, In the presence of a catalytic amount of cobalt(lll) hexafluoroantimonate derived from the optically active 1,2-diphenyl-1,2-ethanediamine, the carbonyl-ene reaction with a variety of alkenes and glyoxal derivatives smoothly proceeded to afford the corresponding homoallylic alcohols in good-to high yields with high enantioselectivities.

引用

页码：1937 / 1939

页数：3

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