Fundamental principles and applications of natural gas hydrates

被引:2632
作者
Sloan, ED [1 ]
机构
[1] Colorado Sch Mines, Ctr Hydrate Res, Golden, CO 80401 USA
关键词
D O I
10.1038/nature02135
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Natural gas hydrates are solid, non-stoichiometric compounds of small gas molecules and water. They form when the constituents come into contact at low temperature and high pressure. The physical properties of these compounds, most notably that they are non-flowing crystalline solids that are denser than typical fluid hydrocarbons and that the gas molecules they contain are effectively compressed, give rise to numerous applications in the broad areas of energy and climate effects. In particular, they have an important bearing on flow assurance and safety issues in oil and gas pipelines, they offer a largely unexploited means of energy recovery and transportation, and they could play a significant role in past and future climate change.
引用
收藏
页码:353 / 359
页数:7
相关论文
共 44 条
[1]  
[Anonymous], GEOLOGICAL SURVEY CA
[2]  
[Anonymous], 2002, P 4 INT C GAS HYDR
[3]  
Ballard A., 2002, P 4 INT C GAS HYDR
[4]   Formation and decomposition of gas hydrates [J].
Bishnoi, PR ;
Natarajan, V .
FLUID PHASE EQUILIBRIA, 1996, 117 (1-2) :168-177
[5]  
Davidson D. W., 1973, WATER COMPREHENSIVE
[6]   THE ABILITY OF SMALL MOLECULES TO FORM CLATHRATE HYDRATES OF STRUCTURE-II [J].
DAVIDSON, DW ;
HANDA, YP ;
RATCLIFFE, CI ;
TSE, JS ;
POWELL, BM .
NATURE, 1984, 311 (5982) :142-143
[7]   Methane hydrates in quaternary climate change - The clathrate gun hypothesis [J].
Dickens, GR .
SCIENCE, 2003, 299 (5609) :1017-1017
[8]  
Dickens GR, 1997, GEOLOGY, V25, P259, DOI 10.1130/0091-7613(1997)025<0259:ABOGIT>2.3.CO
[9]  
2
[10]   DISSOCIATION OF OCEANIC METHANE HYDRATE AS A CAUSE OF THE CARBON-ISOTOPE EXCURSION AT THE END OF THE PALEOCENE [J].
DICKENS, GR ;
ONEIL, JR ;
REA, DK ;
OWEN, RM .
PALEOCEANOGRAPHY, 1995, 10 (06) :965-971