Methylation of zinc bound thiolates; a model for cobalamine independent methionine synthase

被引：57

作者：

Brand, U ^{[1
]}

Rombach, M ^{[1
]}

Vehrenkamp, H ^{[1
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a807326k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyrazolylborate-zinc-thiolate complexes react under mild conditions with methyl iodide, dimethylsulfate and trimethylsulfonium iodide, liberating the corresponding methyl thioethers; the driving force for these reactions lies in the high nucleophilicity of the zinc-bound thiolates and the low donor quality of thioethers toward zinc.

引用

页码：2717 / 2718

页数：2

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