Development and application of oxygen permeable membrane in selective oxidation of light alkanes

被引:142
作者
Yang, WS [1 ]
Wang, HH [1 ]
Zhu, XF [1 ]
Lin, LW [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
关键词
oxygen permeable membrane; selective oxidation; hydrocarbon conversion; membrane reactor;
D O I
10.1007/s11244-005-3820-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this paper, oxygen permeable membrane used in membrane reactor for selective oxidation of alkanes will be discussed in detail. The recent developments for the membrane materials will be presented, and the strategy for the selection of the membrane materials will be outlined. The main applications of oxygen permeable membrane in selective oxidation of light alkanes will be summarized, which includes partial oxidation of methane (POM) to syngas and partial oxidation of heptane (POH) to produce H-2, oxidative coupling of methane (OCM) to C-2, oxidative dehydrogenation of ethane (ODE) to ethylene and oxidative dehydrogenation of propane (ODP) to propylene. Achievements for the membrane material developments and selective oxidation of light alkanes in membrane reactor in our group are highlighted.
引用
收藏
页码:155 / 167
页数:13
相关论文
共 126 条
[1]   Controlled oxidative coupling of methane by ionic conducting ceramic membrane [J].
Akin, FT ;
Lin, YS .
CATALYSIS LETTERS, 2002, 78 (1-4) :239-242
[2]   Selective oxidation of ethane to ethylene in a dense tubular membrane reactor [J].
Akin, FT ;
Lin, YS .
JOURNAL OF MEMBRANE SCIENCE, 2002, 209 (02) :457-467
[3]   Oxidative coupling of methane in dense ceramic membrane reactor with high yields [J].
Akin, FT ;
Lin, YS .
AICHE JOURNAL, 2002, 48 (10) :2298-2306
[4]   Oxides of the AMO3 and A2MO4-type:: structural stability, electrical conductivity and thermal expansion [J].
Al Daroukh, M ;
Vashook, VV ;
Ullmann, H ;
Tietz, F ;
Raj, IA .
SOLID STATE IONICS, 2003, 158 (1-2) :141-150
[5]   Synthesis, crystal chemistry, and oxygen permeation properties of LaSr3Fe3-xCoxO10 (0 ≤ x ≤ 1.5) [J].
Armstrong, T ;
Prado, F ;
Manthiram, A .
SOLID STATE IONICS, 2001, 140 (1-2) :89-96
[6]  
BALACHANDRAN U, 1995, AM CERAM SOC BULL, V74, P71
[7]   Dense ceramic membranes for partial oxidation of methane to syngas [J].
Balachandran, U ;
Dusek, JT ;
Mieville, RL ;
Poeppel, RB ;
Kleefisch, MS ;
Pei, S ;
Kobylinski, TP ;
Udovich, CA ;
Bose, AC .
APPLIED CATALYSIS A-GENERAL, 1995, 133 (01) :19-29
[8]   Ceramic membrane reactor for converting methane to syngas [J].
Balachandran, U ;
Dusek, JT ;
Maiya, PS ;
Ma, B ;
Mieville, RL ;
Kleefisch, MS ;
Udovich, CA .
CATALYSIS TODAY, 1997, 36 (03) :265-272
[9]   Oxygen permeability of La2Cu(Co)O4+δ solid solutions [J].
Bochkov, DM ;
Kharton, VV ;
Kovalevsky, AV ;
Viskup, AP ;
Naumovich, EN .
SOLID STATE IONICS, 1999, 120 (1-4) :281-288
[10]  
Bouwmeester H. J. M., 1997, HDB SOLID STATE ELEC