A europium(III)-N,N,N',N'-tetrakis(2-pyridylmethyl)-(R)-propylenediamine complex as a new chiral lanthanide NMR shift reagent for aqueous neutral solution

被引：28

作者：

Hazama, R

Umakoshi, K

Kabuto, C

Kabuto, K

Sasaki, Y

机构：

[1] HOKKAIDO UNIV,GRAD SCH SCI,DIV CHEM,KITA KU,SAPPORO,HOKKAIDO 060,JAPAN

[2] TOHOKU UNIV,FAC SCI,INSTRUMENTAL ANAL CTR CHEM,AOBA KU,SENDAI,MIYAGI 98077,JAPAN

[3] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,AOBA KU,SENDAI,MIYAGI 98077,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 01期

关键词：

D O I：

10.1039/cc9960000015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chiral lanthanide shift reagent [(EuCl2)-Cl-III{(R)-tppn}]ClO4 which is structurally characterized by X-ray crystallography, resolves the enantiomer signals of alpha-amino acids in neutral aqueous solution and affords a good relation between the relative signal position of enantiomers and their absolute configurations.

引用

页码：15 / 16

页数：2

共 11 条

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