H+, Na+ and K+ modulated lanthanide luminescent switching of Tb(III) based cyclen aromatic diaza-crown ether conjugates in water

被引:80
作者
Gunnlaugsson, T [1 ]
Leonard, JP [1 ]
机构
[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland
关键词
D O I
10.1039/b307055g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cyclen based aromatic diaza-15-crown-5 and 18-crown-6 ether conjugates 1Tb-4Tb were designed as luminescent switches for sodium and potassium where the delayed Tb(III) emission, occurring as line-like emission bands between 490-622 nm, was 'switched on' upon recognition of these ions in pH 7.4 buffered water solution.
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页码:2424 / 2425
页数:2
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