Isotopic microanalysis of seawater strontium in biogenic calcite to assess subsequent rehomogenisation during metamorphism

被引:16
作者
Adams, CJ
Campbell, HJ
Griffin, WL
机构
[1] Inst Geol & Nucl Sci, Lower Hutt, New Zealand
[2] Macquarie Univ, Sch Earth Sci, GEMOC Natl Key Ctr, N Ryde, NSW 2109, Australia
关键词
ICPMS mass spectrometry; strontium analysis; Sr-87/Sr-86; ratios; biogenic carbonates; Permian; 'Atomodesma';
D O I
10.1016/j.chemgeo.2005.03.007
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Precise LAM-MC-ICPMS in situ microanalyses of Sr-87/(86) Sr ratios in biogenic calcite of the bivalve 'Atomodesma' are reported for 14 horizons in low-grade metasediments of late Early Permian to late Late Permian age in South Island, New Zealand. 'Atomodesma' shells (and associated skeletal echinoderm calcite) in zeolite and possibly to lower prehnite-pumpellyite mineral facies material yield isotopic data that are interpreted as primary seawater Sr-87/Sr-86 values. Data for higher metamorphic grade (probable upper prehnite-pumpellyite to lawsonite-albite facies) samples consistently show evidence of Sr isotopic homogenisation between 'Atomodesma' calcite and host matrix and thus seawater Sr-87/Sr-86 values are not retained in shell debris under any circumstances. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:67 / 82
页数:16
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