''Over the horizon'' SANS: Measurements on near-surface Poiseuille shear-induced ordering of dilute solutions of threadlike micelles

被引:29
作者
Hamilton, WA [1 ]
Butler, PD [1 ]
Hayter, JB [1 ]
Magid, LJ [1 ]
Kreke, PJ [1 ]
机构
[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996
来源
PHYSICA B | 1996年 / 221卷 / 1-4期
基金
美国国家科学基金会;
关键词
D O I
10.1016/0921-4526(95)00943-4
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Although the behavior of a fluid under shear near a surface can be expected to be critically important to its drag and lubrication properties, most shear measurements to date have been of the bulk. This paper outlines the use of a specially developed Poiseuille shear cell at grazing incidence to measure the small-angle neutron scattering (SANS) signal from the first few tens of microns in the interfacial region. We illustrate the technique with measurements made on the near-surface ordering in flow past a quartz surface of dilute surfactant solutions comprising highly extended self-assembling ''thread-like'' micelles.
引用
收藏
页码:309 / 319
页数:11
相关论文
共 18 条
[1]   SHEAR CELL FOR THE STUDY OF LIQUID-SOLID INTERFACES BY NEUTRON-SCATTERING [J].
BAKER, SM ;
SMITH, G ;
PYNN, R ;
BUTLER, P ;
HAYTER, J ;
HAMILTON, W ;
MAGID, L .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1994, 65 (02) :412-416
[2]  
BUTLER PD, IN PRESS MAT RES SOC
[3]   STATICS AND DYNAMICS OF WORM-LIKE SURFACTANT MICELLES [J].
CATES, ME ;
CANDAU, SJ .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1990, 2 (33) :6869-6892
[4]  
de Gennes PG, 1979, SCALING CONCEPTS POL
[5]   ESTIMATION OF INCOHERENT BACKGROUNDS IN SANS STUDIES OF POLYMERS [J].
DUBNER, WS ;
SCHULTZ, JM ;
WIGNALL, GD .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1990, 23 :469-475
[6]  
GRANEK R, 1992, J CHEM PHYS, V96
[7]  
HAMILTON DL, 1994, HDB SOCIAL COGNITION, V2, P1
[8]   SHEAR-INDUCED HEXAGONAL ORDERING OBSERVED IN AN IONIC VISCOELASTIC FLUID IN FLOW PAST A SURFACE (VOL 72, PG 2219, 1994) [J].
HAMILTON, WA ;
BUTLER, PD ;
BAKER, SM ;
SMITH, GS ;
HAYTER, JB ;
MAGID, LJ ;
PYNN, R .
PHYSICAL REVIEW LETTERS, 1995, 74 (02) :335-335
[9]   SHEAR-INDUCED HEXAGONAL ORDERING OBSERVED IN AN IONIC VISCOELASTIC FLUID IN FLOW PAST A SURFACE [J].
HAMILTON, WA ;
BUTLER, PD ;
BAKER, SM ;
SMITH, GS ;
HAYTER, JB ;
MAGID, LJ ;
PYNN, R .
PHYSICAL REVIEW LETTERS, 1994, 72 (14) :2219-2222
[10]   USE OF VISCOUS SHEAR ALIGNMENT TO STUDY ANISOTROPIC MICELLAR STRUCTURE BY SMALL-ANGLE NEUTRON-SCATTERING [J].
HAYTER, JB ;
PENFOLD, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (20) :4589-4593