Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host

被引：42

作者：

Hahn, U

Elhabiri, M

Trabolsi, A

Herschbach, H

Leize, E

Van Dorsselaer, A

Albrecht-Gary, AM

Nierengarten, JF

机构：

[1] Univ Strasbourg, Lab Spectrometrie Masse Bioorgan, Ecole Chim Polymeres & Mat, F-67087 Strasbourg, France

[2] CNRS, F-67087 Strasbourg, France

[3] Univ Strasbourg, Lab Physicochim Bioinorgan, F-67087 Strasbourg, France

[4] Ecole Europeenne Chim Polymeres & Mat, CNRS, UMR 7509, F-67087 Strasbourg, France

[5] CNRS, Grp Chim Fullerenes & Syst Conjugues, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 33期

关键词：

binding studies; crown compounds; fullerenes; host-guest systems; supramolecular chemistry;

D O I：

10.1002/anie.200501249

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) All clicking into place: Self-complementarity between a bis (crown ether) derivative and a bisammonium fullerene leads to the formation of a stable noncovalent macrocyclic 1:1 complex (see schematic representation). The binding constant for this complex is three orders of magnitude larger than that for other closely related systems as a result of the two-center host-guest topography. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5338 / 5341

页数：4

共 50 条

[1]

[Anonymous], 2003, ANGEW CHEM, V115, P705

[2]

Armaroli N, 1998, CHEM-EUR J, V4, P406, DOI 10.1002/(SICI)1521-3765(19980310)4:3<406::AID-CHEM406>3.3.CO

[3]

2-R

[4] A new pyridyl-substituted methanofullerene derivative.: Photophysics, electrochemistry and self-assembly with zinc(II) meso-tetraphenylporphyrin (ZnTPP) [J].

Armaroli, N ;

Diederich, F ;

Echegoyen, L ;

Habicher, T ;

Flamigni, L ;

Marconi, G ;

Nierengarten, JF .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (01) :77-83

[5]

Ashton, 1997, ANGEW CHEM, V109, P1611

[6] Self-assembly of the first fullerene-containing [2]catenane [J].

Ashton, PR ;

Diederich, F ;

GomezLopez, M ;

Nierengarten, JF ;

Preece, JA ;

Raymo, FM ;

Stoddart, JF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (13-14) :1448-1451

[7] Preferential hetero-dimer formation and equilibrium dynamics of self-complementary bifunctional oligo(p-phenylenevinylene) and C60 ureido-pyrimidinone derivatives in solution [J].

Beckers, EHA ;

Schenning, APHJ ;

van Hal, PA ;

El-ghayoury, A ;

Sánchez, L ;

Hummelen, JC ;

Meijer, EW ;

Janssen, RAJ .

CHEMICAL COMMUNICATIONS, 2002, (23) :2888-2889

[8] Singlet-energy transfer in quadruple hydrogen-bonded oligo(p-phenylenevinylene)-fullerene dyads [J].

Beckers, EHA ;

van Hal, PA ;

Schenning, APHJ ;

El-ghayoury, A ;

Peeters, E ;

Rispens, MT ;

Hummelen, JC ;

Meijer, EW ;

Janssen, RAJ .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :2054-2060

[9]

Binsteadt R. A., 1998, SPECFIT PROGRAM GLOB

[10] Fullerohelicates: a new class of fullerene-containing supermolecules [J].

Cardinali, F ;

Mamlouk, H ;

Rio, Y ;

Armaroli, N ;

Nierengarten, JF .

CHEMICAL COMMUNICATIONS, 2004, (14) :1582-1583

← 1 2 3 4 5 →