2D chiral uranyl(VI) coordination polymers with second-harmonic generation response and ferroelectric properties

被引：90

作者：

Xie, YR

Zhao, H

Wang, XS

Qu, ZR

Xiong, RG ^{[1
]}

Xue, XA

Xue, ZL

You, XZ

机构：

[1] Beijing Univ, Dept Chem, State Key Lab Rare Earth Mat Chem & Appl, Beijing 100871, Peoples R China

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 20期

关键词：

chirality; polymers; uranium; crystal engineering; SHG properties;

D O I：

10.1002/ejic.200300483

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in situ hydrothermal reactions Of UO2(NO3)2 with 1-oxo-4-cyanopyridine (ocpy) and ethyl (S)-lactate (e-la) afforded two unprecedented chiral 2D neutral luminescent square grids, uranyl-bis(1-oxo-4-pyridylcarboxylate) UO2(opyca)2 (1) and homochiral uranyl-bis [(S) -lactate] (2). Their solid-state structures, preliminary optical and photoluminescent properties are reported. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

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页码：3712 / 3715

页数：4

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