The sergeants-and-soldiers effect: chiral amplification in naphthalenediimide nanotubes

被引：51

作者：

Anderson, Tom W. ^{[1
]}

Sanders, Jeremy K. M. ^{[1
]}

Pantos, G. Dan ^{[1
]}

机构：

[1] Univ Cambridge, Univ Chem Lab, Cambridge CB2 1EW, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 19期

基金：

英国工程与自然科学研究理事会;

关键词：

PRINCIPLE; HELICITY; OLIGOMERS;

D O I：

10.1039/c0ob00027b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Self-assembling naphthalenediimide (NDI)-based helical organic nanotubes display sergeants-and-soldiers behaviour, chiral monomers imposing a supramolecular structure upon achiral monomers. Several achiral NDI monomers were synthesised and their ability to incorporate into supramolecular nanotubes was studied. Nanotubes containing predominantly the most effective soldier, derived from 1-aminocyclopropane-carboxylic acid, are effective hosts for C-60.

引用

页码：4274 / 4280

页数：7

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