Assembly of Modular Asymmetric Organic-Inorganic Polyoxometalate Hybrids into Anisotropic Nanostructures

被引：94

作者：

Rosnes, Mali H. ^{[2
]}

Musumeci, Chiara ^{[3
]}

Pradeep, Chullikkattil P. ^{[2
]}

Mathieson, Jennifer S. ^{[2
]}

Long, De-Liang ^{[2
]}

Song, Yu-Fei ^{[2
]}

Pignataro, Bruno ^{[1
]}

Cogdell, Richard ^{[4
]}

Cronin, Leroy ^{[2
]}

机构：

[1] Univ Palermo, Dipartimento Chim Fis F Accascina, I-90128 Palermo, Italy

[2] Univ Glasgow, Sch Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

[3] Consorzio Catania Ric, Superlab, I-95121 Catania, Italy

[4] Univ Glasgow, Glasgow Biomed Res Ctr, Glasgow G12 8QQ, Lanark, Scotland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 44期

基金：

英国工程与自然科学研究理事会;

关键词：

CLUSTERS; COMPLEXES; CHEMISTRY; SURFACES;

D O I：

10.1021/ja1066338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymmetrical appended groups, have been synthesized, identified using electrospray mass spectrometry, and isolated using an approach that allows the three AA, BB, and AB compounds to be structurally characterized. Investigation of the self-assembly of the hybrids on hydrophilic surfaces reveals the formation of nanofibres with characteristics that reflect the nature of the substitution of the POM yielding a route to the programmed assembly of anisotropic hybrid nanostructures.

引用

页码：15490 / 15492

页数：3

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