Hydroamination/hydrosilylation sequence catalyzed by titanium complexes

被引：94

作者：

Heutling, A ^{[1
]}

Pohlki, F ^{[1
]}

Bytschkov, I ^{[1
]}

Doye, S ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 19期

关键词：

alkynes; amines; hydroamination; hydrosilylation; titanium;

D O I：

10.1002/anie.200462250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A single precatalyst is used for the sequential combination of the Ti-catalyzed hydroamination of alkynes with the Ti-catalyzed hydrosilylation of imines. In this way alkynes and primary amines are converted efficiently into secondary amines in a fully catalytic one-pot process (see scheme). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2951 / 2954

页数：4

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