Performance improvement of polymer solar cells by using a solvent-treated poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) buffer layer

被引:62
作者
Peng, Bo [1 ,2 ]
Guo, Xia [1 ]
Cui, Chaohua [1 ]
Zou, Yingping [2 ]
Pan, Chunyue [2 ]
Li, Yongfang [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
关键词
ENHANCEMENT; MORPHOLOGY; NETWORK;
D O I
10.1063/1.3600665
中图分类号
O59 [应用物理学];
学科分类号
摘要
Photovoltaic performance of the polymer solar cell (PSC) based on poly(3-hexylthiophene) (P3HT) as donor and [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) as acceptor was improved by using the poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) modification layer treated by ethanol or 2-propanol. Power conversion efficiency (PCE) of the PSC based on P3HT: PCBM (1:1, w/w) with the 2-propanol-treated PEDOT: PSS modification layer reached 4.74%, in comparison with a PCE of 3.39% for the PSC with the PEDOT: PSS layer without the organic solvent treatment. The enhanced performance of the PSCs is attributed to higher conductivity and optimized surface morphology of the PEDOT:PSS layers treated by the organic solvent. (C) 2011 American Institute of Physics. [doi:10.1063/1.3600665]
引用
收藏
页数:3
相关论文
共 16 条
[1]   Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices [J].
Chen, Junwu ;
Cao, Yong .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1709-1718
[2]   High-conductivity poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film for use in ITO-free polymer solar cells [J].
Hsiao, Yu-Sheng ;
Whang, Wha-Tzong ;
Chen, Chih-Ping ;
Chen, Yi-Chun .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (48) :5948-5955
[3]   Inspection of substrate-heated modified PEDOT:PSS morphology for all spray deposited organic photovoltaics [J].
Kim, Kyu-Jin ;
Kim, Yeong-Seon ;
Kang, Won-Seok ;
Kang, Byoung-Ho ;
Yeom, Se-Hyuk ;
Kim, Do-Eok ;
Kim, Jae-Ho ;
Kang, Shin-Won .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (07) :1303-1306
[4]   High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].
Li, G ;
Shrotriya, V ;
Huang, JS ;
Yao, Y ;
Moriarty, T ;
Emery, K ;
Yang, Y .
NATURE MATERIALS, 2005, 4 (11) :864-868
[5]   Conjugated polymer photovoltaic materials with broad absorption band and high charge carrier mobility [J].
Li, Yongfang ;
Zou, Yingping .
ADVANCED MATERIALS, 2008, 20 (15) :2952-2958
[6]   Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology [J].
Ma, WL ;
Yang, CY ;
Gong, X ;
Lee, K ;
Heeger, AJ .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (10) :1617-1622
[7]   Evolution of nanomorphology and anisotropic conductivity in solvent-modified PEDOT:PSS films for polymeric anodes of polymer solar cells [J].
Na, Seok-In ;
Wang, Gunuk ;
Kim, Seok-Soon ;
Kim, Tae-Wook ;
Oh, Seung-Hwan ;
Yu, Byung-Kwan ;
Lee, Takhee ;
Kim, Dong-Yu .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (47) :9045-9053
[8]   Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols [J].
Peet, J. ;
Kim, J. Y. ;
Coates, N. E. ;
Ma, W. L. ;
Moses, D. ;
Heeger, A. J. ;
Bazan, G. C. .
NATURE MATERIALS, 2007, 6 (07) :497-500
[9]   Stable Inverted Polymer/Fullerene Solar Cells Using a Cationic Polythiophene Modified PEDOT:PSS Cathodic Interface [J].
Rider, David A. ;
Worfolk, Brian J. ;
Harris, Kenneth D. ;
Lalany, Abeed ;
Shahbazi, Kevin ;
Fleischauer, Michael D. ;
Brett, Michael J. ;
Buriak, Jillian M. .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (15) :2404-2415
[10]   PEDOT:PSS films with significantly enhanced conductivities induced by preferential solvation with cosolvents and their application in polymer photovoltaic cells [J].
Xia, Yijie ;
Ouyang, Jianyong .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) :4927-4936