Ring-closing olefin metathesis and radical cyclization as competing pathways

被引：39

作者：

Schmidt, B

Pohler, M

Costisella, B

机构：

[1] Univ Dortmund, NMR Spektroskopie, FB Chem Organ Chem, D-44227 Dortmund, Germany

[2] Univ Dortmund, NMR Spektroskopie, FB Chem Gemeinsame Einrichtungen, D-44227 Dortmund, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 04期

关键词：

D O I：

10.1021/jo0353942

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

First and second generation Grubbs' catalyst mediate under other-wise identical conditions two different cyclization modes with high selectivity: a ring-closing metathesis and an atom-transfer radical addition (ATRA) pathway.

引用

页码：1421 / 1424

页数：4

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