Polymorphic one-dimensional (N2H4)2ZnTe:: Soluble precursors for the formation of hexagonal or cubic zinc telluride

被引：44

作者：

Mitzi, DB ^{[1
]}

机构：

[1] IBM Corp, TJ Watson Res Ctr, Yorktown Hts, NY 10598 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 20期

关键词：

D O I：

10.1021/ic050833w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two hydrazine zinc(ll) telluride polymorphs, (N2H4)(2)ZnTe, have been isolated, using ambient-temperature solution-based techniques, and the crystal structures determined: alpha-(N2H4)(2)ZnTe (1) [P21, a = 7.2157(4) angstrom, b = 11.5439(6) angstrom, c = 7.3909(4) angstrom, beta = 101.296(1)degrees, Z = 4] and beta-(N2H4)(2)ZnTe (2) [Pn, a = 8.1301(5) angstrom, b = 6.9580(5) angstrom, c = 10.7380(7) angstrom, beta = 91.703(l)degrees, Z = 4]. The zinc atoms in 1 and 2 are tetrahedrally bonded to two terminal hydrazine molecules and two bridging tellurium atoms, leading to the formation of extended one-dimensional (1-D) zinc telluride chains, with different chain conformations and packings distinguishing the two polymorphs. Thermal decomposition of (N2H4)2ZnTe first yields crystalline wurtzite (hexagonal) ZnTe at temperatures as low as 200 degrees C, followed by the more stable zinc blende (cubic) form at temperatures above 350 degrees C. The 1-D polymorphs are soluble in hydrazine and can be used as convenient precursors for the low-temperature solution processing of p-type ZnTe semiconducting films.

引用

页码：7078 / 7086

页数：9

共 42 条

[1] Electrodeposited thin film ZnTe semiconductors for photovoltaic applications [J].

Arico, AS ;

Silvestro, D ;

Antonucci, PL ;

Giordano, N ;

Antonucci, V .

ADVANCED PERFORMANCE MATERIALS, 1997, 4 (01) :115-125

[2] New software for searching the Cambridge Structural Database and visualizing crystal structures [J].

Bruno, IJ ;

Cole, JC ;

Edgington, PR ;

Kessler, M ;

Macrae, CF ;

McCabe, P ;

Pearson, J ;

Taylor, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :389-397

[3] THE THERMAL-DECOMPOSITION OF HYDROGEN-SULFIDE OVER VANADIUM AND MOLYBDENUM SULFIDES AND MIXED SULFIDE CATALYSTS IN QUARTZ AND THERMAL-DIFFUSION COLUMN REACTORS [J].

CHIVERS, T ;

LAU, C .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1987, 12 (04) :235-243

[4]

COTTON FA, 1980, ADV INORG CHEM, P511

[5]

Daweritz L., 1971, Kristall und Technik, V6, P101, DOI 10.1002/crat.19710060114

[6] Novel inorganic-organic-layered structures: Crystallographic understanding of both phase and morphology formations of one-dimensional CdE (E = S, Se, Te) nanorods in ethylenediamine [J].

Deng, ZX ;

Li, LB ;

Li, YD .

INORGANIC CHEMISTRY, 2003, 42 (07) :2331-2341

[7] The structural, optical, and electrical properties of vacuum evaporated Cu-doped ZnTe polycrystalline thin films [J].

Feng, L ;

Mao, D ;

Tang, J ;

Collins, RT ;

Trefny, JU .

JOURNAL OF ELECTRONIC MATERIALS, 1996, 25 (09) :1422-1427

[8] NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].

GABE, EJ ;

LEPAGE, Y ;

CHARLAND, JP ;

LEE, FL ;

WHITE, PS .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 :384-387

[9] n-ZnSe/p-ZnTe/n-CdSe tandem solar cells [J].

Gashin, P ;

Focsha, A ;

Potlog, T ;

Simashkevich, AV ;

Leondar, V .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1997, 46 (04) :323-331

[10] Development of Cu-doped ZnTe as a back-contact interface layer for thin-film CdS/CdTe solar cells [J].

Gessert, TA ;

Mason, AR ;

Sheldon, P ;

Swartzlander, AB ;

Niles, D ;

Coutts, TJ .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1996, 14 (03) :806-812

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