Bismuth(III) thioether chemistry:: the synthesis and structure of [Bi4Cl12(MeSCH2CH2CH2SMe)4]n•nH2O, a highly unusual network involving Bi4Cl4 rings and bridging dithioether ligands

被引:26
作者
Genge, ARJ [1 ]
Levason, W [1 ]
Reid, G [1 ]
机构
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
关键词
D O I
10.1039/a805674i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of [Bi4Cl12(MeSCH2CH2CH2SMe)(4)].nH(2)O involves BiCl12(eta(1)-MeSCH2CH2CH2SMe)(4) tetrameric units which are linked by bridging dithioether ligands to give a three-dimensional polymeric network; the Bi4Cl4 core is an eight-membered heterocycle which adopts an open cradle conformation.
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页码:2159 / 2160
页数:2
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