Rigid oligoperylenediimide rods:: Anion-π slides with photosynthetic activity

被引：102

作者：

Perez-Velasco, Alejandro ^{[1
]}

Gorteau, Virginie ^{[1
]}

Matile, Stefan ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 05期

关键词：

pi interactions; ion channels; membranes; photosynthesis; supramolecular chemistry;

D O I：

10.1002/anie.200703749

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Slide rules: A new class of membrane-active rigid-rod molecules comprising π-acidic, n-semiconducting oligoperylene-diimides is introduced (see picture). They are able to combine passive anion transport across lipid bilayers with photoactive electron transport in the other direction across intact vesicle membranes. Thus, the compounds demonstrate artificial photosynthetic activity. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：921 / 923

页数：3

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