Synthesis, photophysical properties, and laser behavior of 3-amino and 3-acetamido BODIPY dyes

被引：61

作者：

Liras, Marta

Prieto, Jorge Banuelos

Pintado-Sierra, Mercedes

Arbeloa, Fernando Lopez

Garcia-Moreno, Inmaculada

Costela, Angel

Infantes, Lourdes

Sastre, Roberto

Amat-Guerri, Francisco

机构：

[1] Univ Miguel Hernandez, E-03202 Alicante, Spain

[2] CSIC, Inst Quim Organ, E-28006 Madrid, Spain

[3] Univ Basque Country, Dept Quim Fis, E-48080 Bilbao, Spain

[4] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain

[5] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 21期

关键词：

D O I：

10.1021/ol701674b

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The asymmetrically substituted BODIPY dyes 9a and 9b have been synthesized through a key redox step involving the alpha-nitroso derivative of the starting pyrrol. Both dyes emit fluorescence with quantum yields of ca. 0.7, but only 8b behaves as a good laser dye, with an efficiency of 48% in ethanol solution.

引用

收藏

页码：4183 / 4186

页数：4

相关论文

共 26 条

[1]

Correlations between photophysics and lasing properties of dipyrromethene-BF2 dyes in solution [J].

Arbeloa, TL ;

Arbeloa, FL ;

Arbeloa, IL ;

García-Moreno, I ;

Costela, A ;

Sastre, R ;

Amat-Guerri, F .

CHEMICAL PHYSICS LETTERS, 1999, 299 (3-4) :315-321

[2]

PYRROMETHENE-BF2 COMPLEXES AS LASER-DYES .2. [J].

BOYER, JH ;

HAAG, AM ;

SATHYAMOORTHI, G ;

SOONG, ML ;

THANGARAJ, K ;

PAVLOPOULOS, TG .

HETEROATOM CHEMISTRY, 1993, 4 (01) :39-49

[3]

4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes modified for extended conjugation and restricted bond rotations [J].

Chen, J ;

Burghart, A ;

Derecskei-Kovacs, A ;

Burgess, K .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (10) :2900-2906

[4]

Polymeric solid-state dye lasers:: Recent developments [J].

Costela, A ;

García-Moreno, I ;

Sastre, R .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (21) :4745-4763

[5]

Photophysical and lasing properties of new analogs of the boron-dipyrromethene laser dye PM567 in liquid solution [J].

Costela, A ;

García-Moreno, I ;

Gomez, C ;

Sastre, R ;

Amat-Guerri, F ;

Liras, M ;

Arbeloa, FL ;

Prieto, JB ;

Arbeloa, IL .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (34) :7736-7742

[6]

Experimental studies on the constitution of blood and bilary pigment. III. [J].

Fischer, H ;

Eismayer, K .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1914, 47 :2019-2027

[7]

GARCIAMORENO I, 2007, ADV FUNC MAT, DOI DOI 10.1002/ADFM.20061103

[8]

In vitro demonstration of the heavy-atom effect for photodynamic therapy [J].

Gorman, A ;

Killoran, J ;

O'Shea, C ;

Kenna, T ;

Gallagher, WM ;

O'Shea, DF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (34) :10619-10631

[9]

A pulse radiolysis and pulsed laser study of the pyrromethene 567 triplet state [J].

Gorman, AA ;

Hamblett, I ;

King, TA ;

Rahn, MD .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 130 (2-3) :127-132

[10]

Preparations of C-nitroso compounds [J].

Gowenlock, BG ;

Richter-Addo, GB .

CHEMICAL REVIEWS, 2004, 104 (07) :3315-3340