Stereoselective allylic transposition by means of allylic n-pentenyl ethers.: Part 2:: Synthesis of nitrogen heterocycles

被引：4

作者：

Chouteau, F

Addi, K

Bénéchie, M

Prangé, T

Khuong-Huu, F

机构：

[1] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

[2] UFR Biomed, UPRS A 7031 CNRS, F-93017 Bobigny, France

来源：

TETRAHEDRON | 2001年 / 57卷 / 29期

关键词：

n-pentenyl ethers; stereoselection; intramolecular allylic substitution; pyrrolidines; piperidines; 1,3-allylic effect;

D O I：

10.1016/S0040-4020(01)00602-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereospecific synthesis of optically active substituted pyrrolidines, and piperidines was studied via an intramolecular allylic rearrangement by means of allylic n-pentenyl ethers as leaving groups when reacting with halonium ions. (C) 2001 Elsevier Science Ltd. AU rights reserved.

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收藏

页码：6229 / 6238

页数：10

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