Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases

被引：425

作者：

Enemark, JH ^{[1
]}

Cooney, JJA

机构：

[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA

[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020609d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases are discussed. The structural analogues, reactivity analogues and hydrotris(pyrazolyl)borate complexes were studied. The analogues of the sulfite oxidases family sites and of the DMSO reductase family sites were elaborated. The mechanistic aspect of oxo transfer and relative reactivity of molybdenum and tungsten were also analyzed.

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页码：1175 / 1200

页数：26

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