Preparation and characterisation of aluminium pigments coated with silica for corrosion protection

被引:66
作者
Zhang, Yingchao [1 ]
Ye, Hongqi [1 ]
Liu, Hui [1 ,2 ]
Han, Kai [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
[2] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
基金
中国博士后科学基金;
关键词
Aluminium; Alkaline corrosion; SEM; AFM; COMPOSITE PARTICLE; INHIBITORS; OPTIMIZATION; SURFACE; ACID;
D O I
10.1016/j.corsci.2011.01.027
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Aluminium pigments with a layer of silica were prepared by a sol-gel method using tetraethoxysilane as precursor and ethylenediamine as catalyst. Under the optimum conditions, the corrosion protection factor can reach 99.3% and average grain almost remains the same size after coating, indicating that the coated aluminium pigments have excellent chemical stability and good dispersibility. FTIR and EDS analyses demonstrate that a layer of silica coating has been formed on the flaky aluminium particle. SEM, AFM and BET analyses show that a smooth and dense silica coating layer has been formed. (c) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1694 / 1699
页数:6
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