Air sparging: Air-water mass transfer coefficients

Experiments investigating the mass transfer of several dissolved volatile organic compounds (VOCs) across the air-water interface were conducted using a single-air-channel air-sparging system. Three different porous media were used in the study. Air velocities ranged from 0.2 cm s(-1) to 2.5 cm s(-1). The tortuosity factor for each porous medium and the air-water mass transfer coefficients were estimated by fitting experimental data to a one-dimensional diffusion model. The estimated mass transfer coefficients K-G ranged from 1.79 x 10(-3) cm min(-1) to 3.85 x 10(-2) cm min(-1). The estimated lumped gas phase mass transfer coefficients K(G)a were found to be directly related to the air diffusivity of the vee, air velocity, and particle size, and inversely related to the Henry's law constant of the VOCs. Of the four parameters investigated, the parameter that controlled or had a dominant effect on the lumped gas phase mass transfer coefficient was the air diffusivity of the VOC. Two empirical models were developed by correlating the Damkohler and the modified air phase Sherwood numbers with the air phase Peclet number, Henry's law constant, and the reduced mean particle size of porous media. The correlation developed in this study may be used to obtain better predictions of mass transfer Auras for field conditions.