The reaction of cyclooctatetraene with dimethyldioxirane

被引:12
作者
Murray, RW [1 ]
Singh, M [1 ]
Rath, NP [1 ]
机构
[1] Univ Missouri, Dept Chem, St Louis, MO 63121 USA
关键词
dioxiranes; cycloalkenes; cyclooctenes; epoxidations; epoxides; NMR; oxidations; X-Ray crystal structures;
D O I
10.1016/S0040-4020(99)00160-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of cyclooctatetraene with dimethyldioxirane leads to the formation of four diepoxides, three triepoxides, and two tetraepoxides. The structures of the triepoxides and tetraepoxides were confirmed by x-ray crystallographic analysis. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4539 / 4558
页数:20
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