Modified hectorites and adsorption studies of a reactive dye

被引：57

作者：

Baskaralingam, P. ^{[1
]}

Pulikesi, M. ^{[1
]}

Ramamurthi, V. ^{[1
]}

Sivanesan, S. ^{[1
]}

机构：

[1] Anna Univ, AC Coll Technol, Dept Chem Engn, Madras 25, Tamil Nadu, India

来源：

APPLIED CLAY SCIENCE | 2007年 / 37卷 / 1-2期

关键词：

modified hectorite; reactive dye; adsorption; isotherms; kinetics;

D O I：

10.1016/j.clay.2007.01.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hectorite has been modified by two different cationic surfactants namely cetyldimethyl benzylammonium chloride and cetylpyridinium chloride for the adsorption of an anionic dye, C.I. Reactive Orange 122. The modified hectorites were characterized by XRD, SEM and BET analyses. Batch experiments were carried out for the adsorption process in terms of effect of pH, adsorbent dosage, contact time, effect of salts and different dye concentrations. Experimental results show that acidic pH favours maximum colour removal. The data are well fitted by Langmuir isotherm and the adsorption capacity for cetyldimethyl benzylammonium hectorite (CDBA-hect) and cetylpyridinium hectorite (CP-hect) have been found to be 78 and 84 mg/g respectively. Kinetic studies were fitted with the pseudo-second-order kinetic model. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：207 / 214

页数：8

共 30 条

[1] SHAPE-SELECTIVE SORBENTS BASED ON CLAY-MINERALS - A REVIEW [J].

BARRER, RM .

CLAYS AND CLAY MINERALS, 1989, 37 (05) :385-395

[2] Adsorption of acid dye onto organobentonite [J].

Baskaralingam, P ;

Pulikesi, M ;

Elango, D ;

Ramamurthi, V ;

Sivanesan, S .

JOURNAL OF HAZARDOUS MATERIALS, 2006, 128 (2-3) :138-144

[3] Sorption study of an acid dye from an aqueous solutions using modified clays [J].

Bouberka, Z ;

Kacha, S ;

Kameche, M ;

Elmaleh, S ;

Derriche, Z .

JOURNAL OF HAZARDOUS MATERIALS, 2005, 119 (1-3) :117-124

[4]

CASON R, 1977, Proceedings of the Oklahoma Academy of Science, V57, P116

[5]

Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385

[6] PORE- AND SOLID-DIFFUSION KINETICS IN FIXED-BED ADSORPTION UNDER CONSTANT-PATTERN CONDITIONS [J].

HALL, KR ;

EAGLETON, LC ;

ACRIVOS, A ;

VERMEULEN, T .

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1966, 5 (02) :212-+

[7] METALS IN AQUATIC SYSTEMS [J].

HONEYMAN, BD ;

SANTSCHI, PH .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1988, 22 (08) :862-871

[8]

HOYS, 1998, PROCESS SAF ENV PROT, V74, P332

[9] MULTIPLE STEADY-STATES OF AN ISOTHERMAL CATALYTIC REACTION WITH ELOVICH ADSORPTION [J].

KLUSACEK, K ;

HUDGINS, RR ;

SILVESTON, PL .

CHEMICAL ENGINEERING SCIENCE, 1989, 44 (10) :2377-2381

[10]

Lagergren S., 1898, K. Sven. Vetenskad. Handl, V24, P1

← 1 2 3 →