Influence of counter-ion concentration on properties of electrochemically generated poly-N-methylpyrrole (PNMPy/ClO4)

被引：11

作者：

Cambra, A ^{[1
]}

Redondo, MI ^{[1
]}

Gonzalez-Tejera, MJ ^{[1
]}

机构：

[1] U Complutense, Fac Ciencias Quim, Dept Quim Fis 1, Madrid 28040, Spain

来源：

SYNTHETIC METALS | 2003年 / 139卷 / 01期

关键词：

conducting polymers; electrochemical synthesis; polypyrrole derivatives; POLYPYRROLE; FILMS;

D O I：

10.1016/S0379-6779(02)01245-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This is a study of the relationship observed between the synthesis conditions and polymer properties in electrochemically generated poly-N-methylpyrrole (PNMPy). The best values are given for overpotentials of synthesis and perchlorate concentration that provide a polymer with improved conductivity and electrochemical properties. In this way a film was obtained with a conductivity of 1.3 S m(-1). The morphology. electronic spectrum and stability of the film were determined. An equation was determined relating film thickness and polymerization charge density. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：21 / 27

页数：7

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