Structural and spectral studies on four coordinate copper(II) complexes of 2-benzoylpyridine N(4),N(4)-(butane-1,4-diyl)thiosemicarbazone

被引：145

作者：

Sreekanth, A ^{[1
]}

Kurup, MRP ^{[1
]}

机构：

[1] Cochin Univ Sci & Technol, Dept Appl Chem, Cochin 682022, Kerala, India

来源：

POLYHEDRON | 2003年 / 22卷 / 25-26期

关键词：

thiosemicarbazone; copper(II); electronic spectra; IR spectra; EPR; X-ray crystal structure;

D O I：

10.1016/j.poly.2003.07.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Eight new copper(II) complexes of 2-benzoylpyridine N(4),N(4)-(butane-1,4-diyl)thiosemicarbazone (HBpypTsc) with general stoichiometry CuBpypTscX [X=N-3, Cl, NO3, NCS, ClO4, Br, SH and CN] were synthesized and characterized by IR and UV-Vis spectroscopies. The terdentate nature of the ligand is inferred from the IR spectra. Spin Hamiltonian parameters of the compounds were calculated from the EPR spectra. The structures of the compounds CuBpypTscCl (2), CuBpypTscBr (6) and CuBpypTscSH (7) were solved by single crystal X-ray diffraction. CuBpypTscCl (2) is a centrosymmetric dimer with chloro bridges. The geometry around copper in other two complexes is square planar. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：3321 / 3332

页数：12

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