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Metal-organic replica of fluorite built with an eight-connecting tetranuclear cadmium cluster and a tetrahedral four-connecting ligand

被引：237
作者：
Chun, H
Kim, D
Dybtsev, DN
Kim, K
机构：
[1] Pohang Univ Sci & Technol, Natl Creat Res Initiat Ctr Smart Supramol, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Div Mol & Life Sci, Pohang 790784, South Korea
[3] Inst Inorgan Chem, Novosibirsk 630090, Russia
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 08期
关键词：
cadmium; carboxylate ligands; coordination polymers; metal-organic frameworks; topochemistry;
D O I：
10.1002/anie.200353139
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A non-interpenetrating 3D metal-organic framework, synthesized by a solvothermal reaction of cadmium nitrate and a tetracarboxylate ligand, is the first metal-organic analogue of fluorite (CaF2). In the structure of the title compound, depicted, an eight-connecting tetranuclear cadmium cluster (green sphere) and a tetracarboxylate ligand (brown sphere) play the role of Ca2+ and F- ions, respectively, in fluorite.
引用
收藏
页码：971 / 974
页数：4
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