Cyclocarbopalladation:: Sequential cyclization and C-H activation/Stille cross-coupling in the Pd-5-exo-dig reaction

被引：86

作者：

Bour, C ^{[1
]}

Suffert, J ^{[1
]}

机构：

[1] Univ Strasbourg 1, CNRS, UMR 7081, Fac Pharm, F-67401 Illkirch Graffenstaden, France

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 04期

关键词：

D O I：

10.1021/ol047537s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new cyclization and C-H activation/Stille cross-coupling reaction on a nonactivated aromatic has been discovered. The reaction is regioselective and controlled by the stannylated reagent. Labeling experiments have been performed that provide evidence for a complete transfer of the deuterium through the coordination sphere of palladium.

引用

页码：653 / 656

页数：4

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