N-tosylhydrazones as reagents for cross-coupling reactions:: A route to polysubstituted olefins

被引：342

作者：

Barluenga, José ^{[1
]}

Moriel, Patricia ^{[1
]}

Valdes, Carlos ^{[1
]}

Aznar, Fernando ^{[1
]}

机构：

[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, Oviedo 33071, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 29期

关键词：

Bamford-Stevens reaction; cross-coupling; hydrazones; olefination; palladium;

D O I：

10.1002/anie.200701815

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free partner: No organometallic coupling partner is required for a Pd-catalyzed cross-coupling reaction that employs N-tosylhydrazones as the nucleophilic component (see scheme; Ts = 4-toluenesulfonyl). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5587 / 5590

页数：4

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