N-tosylhydrazones as reagents for cross-coupling reactions:: A route to polysubstituted olefins

被引:342
作者
Barluenga, José [1 ]
Moriel, Patricia [1 ]
Valdes, Carlos [1 ]
Aznar, Fernando [1 ]
机构
[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, Oviedo 33071, Spain
关键词
Bamford-Stevens reaction; cross-coupling; hydrazones; olefination; palladium;
D O I
10.1002/anie.200701815
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metal-free partner: No organometallic coupling partner is required for a Pd-catalyzed cross-coupling reaction that employs N-tosylhydrazones as the nucleophilic component (see scheme; Ts = 4-toluenesulfonyl). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5587 / 5590
页数:4
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