Hydrogen physisorption in metal-organic porous crystals

被引：288

作者：

Panella, B ^{[1
]}

Hirscher, M ^{[1
]}

机构：

[1] Max Planck Inst Met Res, D-70569 Stuttgart, Germany

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 05期

关键词：

D O I：

10.1002/adma.200400946

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen adsorption in microporous solid materials may enable H-2 to be stored at lower pressures than in compressed-gas tanks, and at higher temperatures than for liquid H-2. A new class of metal-organic frameworks (MOFs) with a high specific surface area appears promising for H-2 storage. Here, the H-2-uptake capacity of MOF-5 over a wide pressure range, at room temperature and at 77 K is investigated (see Figure). Adsorption of H-2 exclusively in the micropores of these metal-organic frameworks is demonstrated.

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页码：538 / +

页数：5

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