A Noble-Metalate Bowl: The Polyoxo-6-vanado(V)-7-palladate(II) [Pd7V6O24(OH)2]6-

被引：57

作者：

Izarova, Natalya V. ^{[1
,4
]}

Vankova, Nina ^{[1
]}

Banerjee, Abhishek ^{[1
]}

Jameson, Geoffrey B. ^{[2
]}

Heine, Thomas ^{[1
]}

Schinle, Florian ^{[3
]}

Hampe, Oliver ^{[3
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

[2] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand

[3] KIT, Inst Nanotechnol, Karlsruhe, Germany

[4] Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 42期

关键词：

density functional calculations; inorganic syntheses; palladium; polyoxometalates; vanadium; HETEROPOLY COMPLEXES; BUILDING-BLOCKS; CHEMISTRY; CLUSTERS; APPROXIMATION; POLYOXOANION; FRAGMENTS; ENERGY; GOLD;

D O I：

10.1002/anie.201001738

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Nobly born: The bowl-shaped noble metalate [PdII 7VV 6O24(OH)2] 6-(Pd7V6) comprises seven square-planar Pd IIO4 units as well as four tetrahedral VVO 4 and two square-pyramidal VVO5 addenda units (see picture). The solution stability of Pd7V6 has been demonstrated by 51V NMR spectroscopy, ESI mass spectrometry, and DFT calculations. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7807 / 7811

页数：5

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