Effect of direct liquid water injection and interdigitated flow field on the performance of proton exchange membrane fuel cells

被引:240
作者
Wood, DL [1 ]
Yi, YS [1 ]
Nguyen, TV [1 ]
机构
[1] Univ Kansas, Dept Chem & Petr Engn, Lawrence, KS 66045 USA
关键词
proton exchange membrane fuel cells; humidification; gas distribution; direct liquid water injection; interdigitated flow fields;
D O I
10.1016/S0013-4686(98)00139-X
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Proper water management is vital to ensuring successful performance of proton exchange membrane fuel cells. The effectiveness of the direct liquid water injection scheme and the interdigitated flow field design towards providing adequate gas humidification to maintain membrane optimal hydration and alleviating the mass transport limitations of the reactants and electrode flooding is investigated. It is found that the direct liquid water injection used in conjunction with the interdigitated flow fields as a humidification technique is an extremely effective method of water management. The forced flow-through-the-electrode characteristic of the interdigitated flow field (1) provides higher transport rates of reactant and products to and from the inner catalyst layers, (2) increases the hydration state and conductivity of the membrane by bringing its anode/membrane interface in direct contact with liquid water and (3) increases the cell tolerance limits for excess injected liquid water, which could be used to provide simultaneous evaporative cooling. Experimental results show substantial improvements in performance as a result of these improvements. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3795 / 3809
页数:15
相关论文
共 16 条
[1]  
KOLDE JA, 1995, ELECTROCHEMICAL SOC, V9523, P193
[2]  
NGUYEN T, 1989, ELECTROCHEMICAL SOC, P39
[3]   A gas distributor design for proton-exchange-membrane fuel cells [J].
Nguyen, TV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (05) :L103-L105
[4]   A WATER AND HEAT MANAGEMENT MODEL FOR PROTON-EXCHANGE-MEMBRANE FUEL-CELLS [J].
NGUYEN, TV ;
WHITE, RE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (08) :2178-2186
[5]  
RAISTRICK ID, 1989, Patent No. 4826115
[6]   Low cost electrodes for proton exchange membrane fuel cells - Performance in single cells and Ballard stacks [J].
Ralph, TR ;
Hards, GA ;
Keating, JE ;
Campbell, SA ;
Wilkinson, DP ;
Davis, M ;
StPierre, J ;
Johnson, MC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (11) :3845-3857
[7]  
SASIKUMAR G, 1995, ELECTROCHIM ACTA, V40, P285
[8]  
SCHUTZ PJ, 1989, ELECTROCHEMICAL SOC, P87
[9]   POLYMER ELECTROLYTE FUEL-CELL MODEL [J].
SPRINGER, TE ;
ZAWODZINSKI, TA ;
GOTTESFELD, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) :2334-2342
[10]   PREPARATION OF HIGH-PLATINUM-UTILIZATION GAS-DIFFUSION ELECTRODES FOR PROTON-EXCHANGE-MEMBRANE FUEL-CELLS [J].
TAYLOR, EJ ;
ANDERSON, EB ;
VILAMBI, NRK .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (05) :L45-L46