Stereoselective, nonracemic synthesis of ω-borono-α-amino acids

被引：73

作者：

Collet, S ^{[1
]}

Bauchat, P ^{[1
]}

Danion-Bougot, R ^{[1
]}

Danion, D ^{[1
]}

机构：

[1] Univ Rennes 1, UMR 6510, F-35042 Rennes, France

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(98)00186-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

omega-Unsaturated alpha-amino acids are synthesized through condensation of allyl and propargyl bromides or of 9-bromoundecene with a Ni(II) complex of the Schiff base derived from glycine and BPB. Hydroboration with Ipc(2)BH followed by oxidation with acetaldehyde affords enantiomerically pure omega-borono-alpha-aminocarboxylic acids. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：2121 / 2131

页数：11

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