Spin trapping of hydroxyl radicals on Cu/HY zeolites suspended in aqueous solution

被引：15

作者：

Haeusser, Anette ^{[1
]}

Trautmann, Martin ^{[1
]}

Roduner, Emil ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Phys Chem, D-70569 Stuttgart, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 24期

关键词：

PHASE CATALYTIC-OXIDATION; HYDROGEN-ATOMS; ZSM-5; ZEOLITES; BENZENE; PHENOL; WATER; ION; REDUCTION; CONSTANTS; RESONANCE;

D O I：

10.1039/c1cc11181g

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Hydroxyl radical intermediates are trapped in calcined Cu/HY zeolites in the presence of oxygen and water. This suggests that hydrogen peroxide is formed in situ from oxygen. Bronsted acids enhance the formation of the radicals.

引用

页码：6954 / 6956

页数：3

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