Conductivity studies of plasticized PEO-Lithium chlorate-FIC filler composite polymer electrolytes

被引：38

作者：

Wang, YJ

Pan, Y ^{[1
]}

Wang, L

Pang, MJ

Chen, LS

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China

[2] Zhejiang Univ, Ctr Anal & Measurement, Hangzhou 310027, Peoples R China

来源：

MATERIALS LETTERS | 2005年 / 59卷 / 24-25期

关键词：

PEO; polymer electrolyte; conductivity;

D O I：

10.1016/j.matlet.2005.05.011

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new report of the synthesis of (PEO/plasticizer)LiClO4-Li1.3Al0.3Ti1.7(PO4)(3) polymer electrolyte films prepared by the solution-cast technique is represented in this work. DSC trace revealed that T-g decreased with the increase of plasticizer content in the polymer electrolyte films. SEM morphology showed that the surface morphology of films was relatively smooth and homogeneous. Conductivity studies by EIS measurement indicated that the temperature dependence of ionic conductivity of films followed Vogel-Tamman-Fulcher (VTF) equation. The pre-exponential factor (A) and the pseudo activation energy (E-a) increased with the increase of plasticizer content in the polymer electrolyte films. At the 40 wt.% plasticizer content, A and E-a respectively had a maximum. (C) 2005 Elsevier B.V All rights reserved.

引用

页码：3021 / 3026

页数：6

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