Welded electrochromic conductive polymer nanofibers by electrostatic spinning

被引：109

作者：

Jang, SY

Seshadri, V

Khil, MS

Kumar, A

Marquez, M

Mather, PT

Sotzing, GA

机构：

[1] Univ Connecticut, Inst Mat Sci, Polymer Program, Storrs, CT 06269 USA

[2] Los Alamos Natl Lab, Chem Sci & Technol Div, Los Alamos, NM 87545 USA

[3] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 18期

关键词：

D O I：

10.1002/adma.200500577

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conducting polymer nanofibers with average diameter as low as 119 nm exhibiting electrochromism were prepared via electrospinning of soluble precursor polymer, followed by solid/swollen state oxidative crosslinking. During the crosslinking, the fibers welded together without significant perturbation of the morphology, maintaining the quality and shape of nanofibers. In the conversion process solvent is used to swell the precursor polymer and the nanofibers naturally weld together during conversion. The nanofiber were found to be exhibiting switching times between 2-3 s, 20 fold faster than 1 μm thick electrochemically prepared films.

引用

页码：2177 / 2180

页数：4

共 21 条

[1] Multicolored electrochromism polymers: Structures and devices [J].