Unusual gold(I)-catalyzed isomerization of 3-hydroxylated 1,5-enynes: Highly substrate-dependent reaction manifolds

被引:128
作者
Gagosz, F [1 ]
机构
[1] Ecole Polytech, Synth Organ Lab, F-91128 Palaiseau, France
关键词
D O I
10.1021/ol051397k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The gold(I) isomerization of diversely substituted 3-hydroxylated enynes has led to the discovery of three new unreported skeletal rearrangements furnishing structures such as alkylidene-cyclopentenes, cyclohexadienes or alpha,beta-unsaturated aldehydes under very mild conditions.
引用
收藏
页码:4129 / 4132
页数:4
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