Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions

被引：133

作者：

Braun, T

Perutz, RN

Sladek, MI

机构：

[1] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b106646c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cross-coupling reaction of pentafluoropyridine with tributyl( vinyl) tin affording 2-vinyltetrafluoropyridine by activation of a carbon-fluorine bond is catalysed by [NiF( 2-C5NF4)( PEt3)(2)]; a similar reaction is observed with 2,3,5,6- tetrafluoropyridine.

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页码：2254 / 2255

页数：2

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