Superbulky ligands and trapped electrons: New perspectives in divalent lanthanide chemistry

被引：32

作者：

Meyer, Gerd ^{[1
]}

机构：

[1] Univ Cologne, Dept Chem Anorgan Chem, D-50939 Cologne, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 27期

关键词：

electron localization; lanthanides; lanthanum; samarium; superbulky ligands;

D O I：

10.1002/anie.200801444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Spectacular developments in recent years, especially the discovery of an anionic complex of divalent lanthanum, in which the electron is trapped in a localized 5d1 SOMO (see structure of the anion of [K([2.2.2]crypt)][LaCp″3] (Cp″ = 1,3-(SiMe3) 2C5H3); La red, Cgray, Si black), have brought new impetus to the solution chemistry of divalent lanthanides. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4962 / 4964

页数：3

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