Stabilization of the merocyanine form of photochromic compounds in fluoro alcohols is due to a hydrogen bond

被引:53
作者
Suzuki, T [1 ]
Lin, FT [1 ]
Priyadashy, S [1 ]
Weber, SG [1 ]
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA USA
关键词
D O I
10.1039/a806316h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluoroalcohols [1,1,1,3,3,3-hexafluoropropan-2-ol (HFP), 2,2,2-trifluoroethanol (TFE) and 2-fluoroethanol (FE)], acting as Lewis acids, stabilize the Jc-conjugated, colored merocyanine forms of spiropyran and spirooxazine photochromic compounds as metal ions do.
引用
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页码:2685 / 2686
页数:2
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