Compatibilization of polystyrene and polyamide 6 mixtures with poly(styrene-co-sodium acrylate)

被引:13
作者
Rodríguez-Ríos, H
Nuño-Donlucas, SM
Puig, JE
González-Núñez, R
Schulz, PC
机构
[1] Univ Guadalajara, Dept Ingn Quim, Guadalajara 44430, Jalisco, Mexico
[2] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
关键词
compatibilization; ionomers; morphology; blends;
D O I
10.1002/app.13332
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work, the compatibilization of polystyrene-and-nylon 6 mixtures with the ionomer, poly(styrene-co-sodium acrylate), is investigated. The ionomer was synthesized by emulsion polymerization. Scanning electron microscopy reveals that an appreciable size reduction of the dispersed phase is achieved in the whole composition range, when small amounts of the ionomer were added. IR spectroscopy and water absorption tests disclose that a chemical reaction occurs between the carboxylic group of the ionomer and the terminal amine group of the polyamide 6, which allows the compatibilization process. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码:1736 / 1745
页数:10
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