In situ high pressure study of ZIF-8 by FTIR spectroscopy

被引：720

作者：

Hu, Yue ^{[1
]}

Kazemian, Hossein ^{[2
]}

Rohani, Sohrab ^{[2
]}

Huang, Yining ^{[1
]}

Song, Yang ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Western Ontario, Dept Chem & Biochem Engn, London, ON N6A 5B9, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 47期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS;

D O I：

10.1039/c1cc15525c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ZIF-8 as a promising storage material was investigated at high pressures up to similar to 39 GPa by in situ FTIR spectroscopy for the first time. Structural modifications are found to be reversible in a low-pressure region but irreversible in a high-pressure region. Overall, the ZIF-8 framework exhibits an unusual chemical stability even under extreme compression.

引用

页码：12694 / 12696

页数：3

共 16 条

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