Comparison of thermal degradation products from real municipal waste plastic and model mixed plastics

被引:63
作者
Bhaskar, T [1 ]
Uddin, A [1 ]
Murai, K [1 ]
Kaneko, J [1 ]
Hamano, K [1 ]
Kusaba, T [1 ]
Muto, A [1 ]
Sakata, Y [1 ]
机构
[1] Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 7008530, Japan
关键词
municipal waste plastic; thermal degradation; poly(ethylene terephalate);
D O I
10.1016/S0165-2370(03)00027-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The thermal degradation of real municipal waste plastic (MWP) obtained from Sapporo, Japan and model mixed plastics was carried out at 430 degreesC in atmospheric pressure by batch operation. The chlorinated hydrocarbons found in PE/PP/PS/PVC [poly(ethylene)/poly(propylene)/poly(styrene)/poly(vinyl chloride)] degradation liquid products were also observed in PE/PP/PS/PVC/PET (poly(ethylene terephalate)) and MWP degradation liquid products. The presence of PET in MWP produced the additional chlorinated hydrocarbons, which are similar to the chlorinated hydrocarbons observed during the PE/PP/PS/PVC/PET degradation liquid products. In addition, the presence of PET facilitated the formation of more organic chlorine content in liquid products and drastic decrease in the formation of inorganic chlorine content. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:579 / 587
页数:9
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