Alkynoates as a source of reactive alkylinides for aldehyde addition reactions

被引：41

作者：

de Armas, P

García-Tellado, F

Marrero-Tellado, JJ

Tejedor, D

Maestro, MA

Gonzalez-Platas, J

机构：

[1] CSIC, Inst Prod Nat & Agrobiol, E-38206 San Cristobal la Laguna, Santa Cruz Tene, Spain

[2] Univ La Laguna, Inst Bioorgan Antoni Gonzalez, E-38206 San Cristobal la Laguna, Santa Cruz Tene, Spain

[3] Univ A Coruna, Serv Rayos Apoyo Invest X, E-15071 La Coruna, Spain

[4] Univ La Laguna, Dpto Fis Fundamental 2, Serv Integrado Difracc, SIDIX, E-38206 San Cristobal la Laguna, Santa Cruz Tene, Spain

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol015951b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHCIS] The reaction of activated alkynes with carbonyl compounds in the presence of a catalytic amount of a nucleophile leads to enol-protected functionalized propargyl alcohols and 1,3-dioxolane compounds by way of a mild carbon-carbon bond formation reaction.

引用

页码：1905 / 1908

页数：4

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[Anonymous], ORGANOMAGNESIUM METH

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[Anonymous], ORGANOLITHIUM METHOD

[3] Alkoxide-catalyzed addition of terminal alkynes to ketones [J].