Double carbonylation of aryl iodides with diethylamine catalyzed by dinuclear palladium complexes

被引：49

作者：

Tsukada, N ^{[1
]}

Ohba, Y ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Biomol Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 687卷 / 02期

关键词：

carbon monoxide; double carbonylation; aryl iodide; dinuclear palladium complexes;

D O I：

10.1016/j.jorganchem.2003.08.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dinuclear palladium complexes bridged by a novel PNNP ligand, N,N'-bis[(2-diphenylphosphino)phenylformamidinate (dpfam), were found to be very efficient and selective catalysts for the double carbonylation of iodobenzene with diethylamine using K3PO4 as base and 1,4-dioxane as solvent with a TON up to 10(5) and selectivity of 96%. (C) 2003 Published by Elsevier B.V.

引用

页码：436 / 443

页数：8

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