Mechanochemical synthesis of ternary fluorides with perovskite structures

被引：23

作者：

Lee, J ^{[1
]}

Zhang, QW ^{[1
]}

Saito, F ^{[1
]}

机构：

[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 07期

关键词：

D O I：

10.1246/cl.2001.700

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanochemical synthesis of ternary zinc fluorides, AZnF(3) (A = K, Na and NH,) with perovskite structures was attempted by grinding equimolar mixtures of zinc fluoride (ZnF2) and one of fluorides, i.e., potassium fluoride (KF), sodium fluoride (NaF) and ammonium fluoride (NH4F), respective ly, in air using a planetary ball mill. The grinding enables us to synthesize these compounds, and the crystallinity of them is improved as the grinding progresses. The synthesized materials formed in the ground mixtures seem to be agglomerates of fine particles having diameters of about several tens nanometer.

引用

页码：700 / 701

页数：2

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